What is the regulatory status of hexabromocyclododecane (HBCDD) in the EU, the US and China?
Summary: HBCDD is effectively banned in the EU and China as a Stockholm Convention persistent organic pollutant (POP). In the US it isn't banned: EPA has found unreasonable risk, but I found no final risk-management rule.
How I searched: I searched by name, "HBCDD"/"HBCD" and CAS 25637-99-4 / 3194-55-6. EU sources were the ECHA Candidate List, Annex XIV and authorisation decisions, Annex XVII, CLP Annex VI, the EU POPs Regulation list and the EU PIC (export/import) register. For the US I used the TSCA Inventory, Significant New Use Rules (SNURs), EPA's TSCA risk evaluations and the 2024 Chemical Data Reporting (CDR) cycle. For China I used the Ministry of Ecology and Environment (MEE) lists listed below. Two gaps (the US rule and China's "new pollutants" list) were checked on epa.gov, federalregister.gov and mee.gov.cn; those points rest on search snippets only.
EU: banned under the POPs Regulation
- POPs Regulation (EU) 2019/1021: listed in Annex I Part A and Annex IV since 01-Mar-2016. That means it's prohibited, and waste concentration limits apply [1][2].
- REACH Candidate List: added 28-Oct-2008 as PBT (Art. 57(d)). The group entry covers the 25637-99-4 substance and the individual isomers [3][4].
- Annex XIV (authorisation list): entry 03, sunset date 21-Aug-2015 [5]. The one authorisation (C(2015) 9812, held by EPS/polystyrene producers) has expired [6].
- Annex XVII: no HBCDD entry found.
- CLP Annex VI (index 602-109-00-4): classified Repr. 2 (H361) and Lact. (H362), signal word Warning, applied since 01-Dec-2013 (ATP03) [7][8].
- PIC Regulation 649/2012: in Annex I Part 3 and Annex V, so it is banned for export (Rotterdam Convention Annex III) [9].
- Stockholm Convention: listed in Annex A (elimination) by decision SC-6/13 [10].
US: unreasonable risk found, but no ban
- TSCA Inventory: both CAS numbers are ACTIVE and carry the "S" flag; 3194-55-6 also carries "TP" [11][12].
- SNUR (40 CFR 721), 80 FR 57293, effective 2015-11-23: anyone making, importing or processing HBCD for consumer textiles (other than in motor vehicles) must notify EPA 90 days in advance [13].
- TSCA section 6(b) risk evaluation:
- HBCD was one of the first 10 chemicals; EPA issued its risk evaluation in September 2020 [14][15].
- The June 2022 revision concludes that HBCD as a whole presents unreasonable risk to health and the environment [16].
- The risk is driven by import, processing (formulation, articles, recycling of XPS/EPS foam), building-material installation and demolition. No unreasonable risk to consumers was found [17][18].
- Section 6(a) risk-management rule: EPA says it will propose one (Federal Register snippet). I found no official record of a proposed or final rule.
China: banned under Stockholm implementation
- MEE et al. Announcement 2016 No. 84: production, use, import and export banned from 26 Dec 2016. Two exemptions applied: EPS/XPS in buildings, under registration that in principle ended 25 Dec 2021; and laboratory-scale research or reference standards [19].
- Customs trade bans: included in the 8th Prohibited Import Goods Catalogue and 7th Prohibited Export Goods Catalogue (MOFCOM Announcement 2023 No. 21, 2023-06-08). HS code is 2903890020; the five CAS numbers listed are 25637-99-4, 3194-55-6 and 134237-50-6/51-7/52-8 [20].
- Priority Controlled Chemicals List (Batch 1): entry PC012, Announcement 2017 No. 83 [21].
- Key Controlled New Pollutants List (2023): in force from 1 March 2023. HBCDD is in the "phased-out" category: production, processing/use, import and export are prohibited (MEE search snippet).
- IECSC inventory: listed in the 2013 edition (CAS 25637-99-4) [22]. Being listed doesn't override the bans above.
- Severely Restricted Toxic Chemicals List (2023 edition): no HBCDD entry found.
Sources:
SOURCES · 22
- [1]Hexabromocyclododecane (HBCDD) · p.2ECHA
- [2]Hexabromocyclododecane · p.2ECHA
- [3]Hexabromocyclododecane (HBCDD) · p.2SVHC
- [4]Hexabromocyclododecane · p.2SVHC
- [5]Hexabromocyclododecane · p.2Annex XIV
- [6]Hexabromocyclododec ane (HBCDD), C(2015) 9812 · p.1Annex XIV
- [7]gamma-hexabromocyclododecane (CLP Index 602-109-00-4) · p.2CLH
- [8]gamma-hexabromocyclododecane (CLP Index 602-109-00-4) · p.2CLH
- [9]Hexabromocyclododecane (ECHA substance id 100.042.848) · p.1EU/ECHA
- [10]Hexabromocyclododecane (HBCDD) (Annex A) · p.1BRS
- [11]Cyclododecane, hexabromo- (CAS 25637-99-4)EPA
- [12]Cyclododecane, 1,2,5,6,9,10-hexabromo- (CAS 3194-55-6)EPA
- [13]Significant New Use Rule for Hexabromocyclododecane and 1,2,5,6,9,10-Hexabromocyclododecane · p.1EPA
- [14]Cyclic Aliphatic Bromide Cluster (HBCD) (scope) · p.8EPA
- [15]Cyclic Aliphatic Bromide Cluster (HBCD) (revised_risk_determination) · p.2EPA
- [16]Cyclic Aliphatic Bromide Cluster (HBCD) (revised_risk_determination) · p.1EPA
- [17]Cyclic Aliphatic Bromide Cluster (HBCD) (final_risk_evaluation) · p.43EPA
- [18]Cyclic Aliphatic Bromide Cluster (HBCD) (final_risk_evaluation) · p.42EPA
- [19]关于《<关于持久性有机污染物的斯德哥尔摩公约>新增列六溴环十二烷修正案》生效的公告 · p.1MEE
- [20]商务部 海关总署 生态环境部关于公布《禁止进口货物目录(第八批)》和《禁止出口货物目录(第七批)》的公告 · p.1MEE
- [21]PC012 六溴环十二烷 · p.1MEE
- [22]六溴环十二烷 (base2013 public) · p.2361MEE/SCC